Performance Evaluation of Esters Extracted from Waste Cooking Palm Oil on the Rheology, Filtration and Mud Cake Properties of Water Based Drilling Mud

Authors

  • Muhammad Emre Bin Mohd Nazran Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, Kuantan, Pahang. Malaysia
  • Norida Binti Ridzuan Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, Kuantan, Pahang. Malaysia
  • Mohd Shahrul Azuar Bin Mat Roseh Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, Kuantan, Pahang. Malaysia
  • Awang Harun Alrashid Bin Hamzah Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, Kuantan, Pahang. Malaysia

DOI:

https://doi.org/10.56532/mjsat.v6i1.730

Keywords:

Waste Cooking Palm Oil, Bio ester, Water-Based Mud, Filtration Control, Rheology

Abstract

The synthesis of high-purity biodegradable esters from Waste Cooking Palm Oil (WCPO) represents a transformative shift toward sustainable drilling operations. By utilizing acid-catalyzed transesterification, this research successfully converts a low-value waste stream into a functional chemical additive capable of enhancing Water-Based Mud (WBM) performance. A critical aspect of this innovation is the achieved chemical purity of 98.8%, which ensures the bioester remains stable under high-shear environments. While commercial ester benchmarks at 4% concentration resulted in 15 mL fluid loss, the synthesized WCPO ester achieved a 61.5% improvement in fluid loss compared to the base mud, reducing loss to 10 mL and forming an ultra-thin 2/32-inch mudcake. Furthermore, rheological analysis confirmed that the ester stabilizes the Yield Point (YP) and Plastic Viscosity (PV) within operational limits, maintaining a predictable density range (7.7 to 8.5 ppg) compared to the erratic fluctuations observed in commercial alternatives. Although current results validate performance under Low-Pressure Low-Temperature (LPLT) conditions, this work establishes a foundation for future High-Pressure High-Temperature (HPHT) thermal stability validation. Therefore, this study demonstrates a viable waste-to-value pathway that supports the Malaysian circular economy and local SME scalability by providing a low-energy (65°C), cost-effective alternative to synthetic lubricants.

References

Said, M. M., & El-Sayed, A.-A. H. (2018). The use of palm oil fatty acid methyl ester as a base fluid for a flat rheology high-performance drilling fluid. Journal of Petroleum Science and Engineering, 166, 969–983. doi:https://doi.org/10.1016/j.petrol.2018.03.101

O. F. Afolabi, I. A. Said, and N. H. El Sayed, "Vegetable oil derivatives as lubricants for torque and drag reduction in water based drilling fluids," Arabian Journal of Chemistry, vol. 15, no. 3, p. 103610, 2022. doi:https://doi.org/10.1016/j.arabjc.2021.103610

M. U. H. Suzihaque et al., "A review on the utilization of palm oil waste as a lubricant for drilling fluids," Materials Today: Proceedings, vol. 63, pp. S450-S456, 2022. doi:https://doi.org/10.1016/j.matpr.2022.03.541

S. Agnihotri, J. P. Soni, and V. K. Sangal, "Optimized catalyst selection for esterification of waste cooking oil," Process Safety and Environmental Protection, vol. 170, pp. 112-125, 2023. doi:https://doi.org/10.1016/j.psep.2022.11.077

M. M. Gui, K. T. Lee, and S. Bhatia, "Feasibility of edible oil vs. waste edible oil as biodiesel feedstock," Energy, vol. 33, no. 11, pp. 1646-1653, 2008. doi:https://doi.org/10.1016/j.energy.2008.06.002

J. F. Argillier et al., "Performance of a New Biodegradable Ester Based Lubricant for Improving Drilling Operations with Water Based Muds," SPE, 1997.

H. Hamze, M. Akia, and F. Yazdani, "Optimization of biodiesel production from the waste cooking oil," Process Safety and Environmental Protection, vol. 94, pp. 1-10, 2015. doi:https://doi.org/10.1016/j.psep.2014.12.005

F. F. Khor et al., "Malaysian Palm Oil as a Base for Drilling Fluids," Universiti Teknologi Malaysia, 2000.

R. Abd Rabu et al., "Transesterification of waste cooking oil: Process optimization," Energy Conversion and Management, vol. 65, pp. 764-769, 2013. doi:https://doi.org/10.1016/j.enconman.2012.01.033

M. E. M. Nazran, "Ester Extraction from Waste Cooking Palm Oil (WCPO) for Enhanced Water Based Drilling Mud Performance," Undergraduate Thesis, Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, 2026.

S. Rawat and S. Garia, "A review on the application of vegetable oil-based drilling fluids: Sustainability and performance," J. Pet. Sci. Eng., 2023. doi:https://doi.org/10.1016/j.petrol.2022.111162

Recommended Practice for Field Testing Water-based Drilling Fluids, API RP 13B-1, 5th ed., American Petroleum Institute, 2019.

N. S. El-Gendy and J. G. Speight, Handbook of Refinery Desulfurization. CRC Press, 2015. doi:https://doi.org/10.1201/b19159

K. G. Georgogianni, M. G. Kontominas, E. Tegou, D. Avlonitis, and V. Glaus, "Biodiesel production from used cooking oil by conventional, non-catalytic and supercritical methods," Fuel Process. Technol., 2009. doi:https://doi.org/10.1016/j.fuproc.2009.03.014

M. Canakci, "The potential of restaurant waste lipids as biodiesel feedstocks," Bioresour. Technol., 2007. doi:https://doi.org/10.1016/j.biortech.2005.11.022

J. M. Encinar, J. F. González, and A. Rodríguez-Reinares, "Biodiesel from used frying oil. Variables affecting the yields and characteristics of the ethyl esters," Ind. Eng. Chem. Res., 2002. doi:https://doi.org/10.1021/ie010214v

M. R. R. Koay et al., "Technical and economic assessment of waste cooking oil conversion," Energy Rep., 2022. doi:https://doi.org/10.1016/j.egyr.2022.01.144

T. J. S. Kean, Esterification of Fatty Acids: Kinetic and Thermal Management. Elsevier, 2020. doi:https://doi.org/10.1016/C2018-0-03975-6

P. S. S. J. Soni, "Optimization of washing cycles in biodiesel purification," J. Clean. Prod., 2021. doi:https://doi.org/10.1016/j.jclepro.2020.124231

A. K. Agarwal, "Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines," Prog. Energy Combust. Sci., 2007. doi:https://doi.org/10.1016/j.pecs.2006.08.003

H. C. H. Darley and G. R. Gray, Composition and Properties of Drilling and Completion Fluids. Gulf Professional Publishing, 2017.

G. V. Chilingarian and P. Vorabutr, Drilling and Drilling Fluids. Elsevier Scientific Publishing, 1983.

J. P. Plank, "Water-based drilling fluids: Performance and environmental aspects," Oil Gas Eur. Mag., 1992.

N. J. Adams, Drilling Engineering: A Complete Well Planning Approach. PennWell Books, 1985.

D. C. Montgomery, Design and Analysis of Experiments, 9th ed. John Wiley & Sons, 2017.

M. F. Ahmad, S. S. Rahman, and I. Ismail, "Integrated wellbore stability analysis for narrow pressure window drilling in the Malay Basin," J. Pet. Sci. Eng., vol. 165, pp. 755-768, 2018. doi:https://doi.org/10.1016/j.petrol.2018.02.062

Caenn, R., Darley, H.C.H., Gray, G.R. Composition and Properties of Drilling and Completion Fluids. 7th ed. Gulf Professional Publishing, 2017.

Schramm, L.L. Emulsions: Fundamentals and Applications in the Petroleum Industry. ACS Symposium Series, 1992. doi:https://doi.org/10.1021/bk-1992-0242

Amanullah, M., Al-Arfaj, M. Lubricants for water-based drilling fluids. SPE Papers. doi:https://doi.org/10.2118/103874-MS

API Recommended Practice 13B-1. Field Testing Water-Based Drilling Fluids. American Petroleum Institute.

API Recommended Practice 13B-2. Field Testing Oil-Based Drilling Fluids. American Petroleum Institute.

Gui, M.M., Lee, K.T., Bhatia, S. Feasibility of edible oil vs non-edible oil biodiesel. Energy, 2008. doi:https://doi.org/10.1016/j.energy.2008.06.002

Atabani, A.E., et al. Biodiesel production optimization review. Renewable and Sustainable Energy Reviews, 2012. doi:https://doi.org/10.1016/j.rser.2012.01.003

Vogel, A.I. Practical Organic Chemistry. Longman.

Bourgoyne, A.T., et al. Applied Drilling Engineering. SPE Textbook Series.

Van Olphen, H. An Introduction to Clay Colloid Chemistry. Wiley, 1977.

Bergaya, F., Lagaly, G. Handbook of Clay Science. Elsevier. doi:https://doi.org/10.1016/B978-0-08-044393-5.X5000-0

PETRONAS drilling operational practices (industry standards context).

Downloads

Published

2026-03-25

Issue

Section

Articles

How to Cite

[1]
“Performance Evaluation of Esters Extracted from Waste Cooking Palm Oil on the Rheology, Filtration and Mud Cake Properties of Water Based Drilling Mud”, Malaysian J. Sci. Adv. Tech., vol. 1, no. 1, pp. 1–7, Mar. 2026, doi: 10.56532/mjsat.v6i1.730.